Lesson 1-2e · Reaction Types & Balancing

Keep the atoms, balance the reaction.

A chemical reaction does not create atoms. It remodels them. Bonds break and new bonds form, but the building blocks never vanish. The Law of Conservation of Mass says every atom present before a reaction is still there afterward. You show this by balancing the equation with coefficients. By the end, you can sort reactions into five patterns and balance an equation.

Na Na + Cl Cl 2 Na(s) + Cl₂(g) Products Form Here (Pending Reaction) LEDGER • Sodium: 2 in reactants | Chlorine: 2 in reactants • 0 products
Before: Two solid sodium atoms and one diatomic chlorine gas molecule ready to collide.
Na⁺ Na⁺ e⁻ e⁻ Cl⁻ Cl⁻ Valence Electron Transfer Ions Assembling... IN TRANSIT • 2 Sodium atoms, 2 Chlorine atoms • Mass is fully conserved
Rearrangement: Each sodium transfers one electron to a chlorine atom, forming Na⁺ and Cl⁻ ions.
Reactants Consumed 0 unreacted Na or Cl₂ Na⁺ Cl⁻ Cl⁻ Na⁺ 2 NaCl(s) lattice LEDGER MATCH • Sodium: 2 left = 2 right • Chlorine: 2 left = 2 right [balanced]
After: Opposite ions lock into a stable 2 NaCl crystal lattice with 100% atom conservation.

atoms are rearranged, never created or destroyed · the ledger counts stay identical

Alignment
HS-PS1-2 Construct and revise an explanation for the outcome of a simple chemical reaction based on the outermost electron states of atoms, trends in the periodic table, and knowledge of the patterns of chemical properties.
HS-PS1-7 Use mathematical representations to support the claim that atoms, and therefore mass, are conserved during a chemical reaction.
Objective
You can sort reactions into five patterns. You can balance an equation with coefficients and check it with an atom count.
Scope
Synthesis, decomposition, single replacement, double replacement and combustion. Acid-base reactions are recognized as double replacement. Balancing changes coefficients, never subscripts.

Core Claims

  • Reaction types: Reactions fall into five patterns: synthesis, decomposition, single replacement, double replacement and combustion. An acid-base reaction is a double replacement.
  • Law of conservation: Atoms are never created or destroyed. Every atom in the reactants appears in the products.
  • Balancing rules: Change coefficients to level the atom count. Never change a subscript, because it defines the substance.

The five reaction blueprints

SYN A + B A B A + B → AB DEC A B A + B AB → A + B S-R A + B C A C + B A+BC→AC+B D-R A B + C D A D + C B AB+CD→AD+CB COMB fuel + O₂ CO₂ + H₂O fuel+O₂→CO₂+H₂O

Retrieval Checklist

  • Sort a reaction into one of the five patterns.
  • Balance an equation by changing coefficients.
  • Check that the atoms match on both sides of the arrow.

Five blueprints of rearrangement.

Chemists do not memorize millions of reactions. They sort reactions into a few blueprints. Look at how the reactants combine and you can predict what kind of products form.

Five reaction blueprints

Synthesis

A + B → AB

GENERIC MODEL A + B A B EXAMPLE: 2 Mg + O₂ → 2 MgO Mg Mg + Mg O Mg O

Example: 2 Mg + O₂ → 2 MgO

Signature: Two things go in and one thing comes out. Elements or simple compounds combine into a single compound.

Decomposition

AB → A + B

GENERIC MODEL A B A + B EXAMPLE: 2 H₂O₂ → 2 H₂O + O₂ +

Example: 2 H₂O₂ → 2 H₂O + O₂

Signature: One reactant, several products. It usually needs heat, electricity or a spark to break it apart.

Single Replacement

A + BC → AC + B

GENERIC MODEL A + B C + EXAMPLE: Zn + CuSO₄ → ZnSO₄ + Cu Zn + Cu SO₄ Zn SO₄ + Cu

Example: Zn + CuSO₄ → ZnSO₄ + Cu

Signature: A lone element sits on each side of the arrow. One element pushes another out of its compound and takes its place.

Double Replacement

AB + CD → AD + CB

GENERIC MODEL + + EXAMPLE: AgNO₃ + NaCl → AgCl + NaNO₃ Ag NO₃ + Na Cl Ag Cl + Na NO₃

Example: AgNO₃ + NaCl → AgCl + NaNO₃

Signature: Two compounds swap partners. Each positive ion pairs with the other negative ion. A solid precipitate often drops out of solution.

Combustion

fuel + O₂ → CO₂ + H₂O

GENERIC MODEL fuel + CO₂ + H₂O EXAMPLE: CH₄ + 2 O₂ → CO₂ + 2 H₂O + +

Example: CH₄ + 2 O₂ → CO₂ + 2 H₂O

Signature: O₂ is on the left. CO₂ and H₂O are on the right. If those three appear and heat is released, the reaction is combustion.

Acid-Base Neutralization

acid + base → salt + water

GENERIC MODEL HX + MOH MX + H₂O EXAMPLE: HCl + NaOH → NaCl + H₂O + +

Example: HCl + NaOH → NaCl + H₂O

Signature: An acid (written with H first) meets a base (written with -OH). Water and an ionic salt form.

The name "neutralization" is beyond this course's assessment boundary. You will not be asked to classify a reaction as neutralization. Recognize it as a double replacement.

Common mistake

Hunting for a lone element in every reaction. If both reactants are compounds, the reaction cannot be single replacement. The two compounds swap partners, so it is double replacement.

Practice classifying reactions

Adjust coefficients, lock the subscripts.

To keep the atoms equal, you might want to change a subscript inside a formula. Never do this. Subscripts define the chemical identity of a substance. Change H2O to H2O2 and you model hydrogen peroxide, a bleach, instead of water. You cannot change the ingredients to balance the scale.

Instead, change the coefficients, the numbers in front of formulas. A coefficient multiplies the whole molecule. A 2 in front of H2O (2 H2O) means two separate water molecules. That doubles the hydrogen and oxygen atoms and keeps the identity.

Walkthrough: balancing methane combustion

CH₄ + O₂ → CO₂ + H₂O Element Left Right Carbon (C) 1 1 Hydrogen (H) 4 2 Oxygen (O) 2 3 CH₄ + O₂ → CO₂ + 2 H₂O Element Left Right Carbon (C) 1 1 Hydrogen (H) 4 4 Oxygen (O) 2 4 CH₄ + 2 O₂ → CO₂ + 2 H₂O Element Left Right Carbon (C) 1 1 Hydrogen (H) 4 4 Oxygen (O) 4 4 1 CH₄ + 2 O₂ → 1 CO₂ + 2 H₂O Element Left Right Carbon (C) 1 1 Hydrogen (H) 4 4 Oxygen (O) 4 4
The one idea to hold onto

Think of each compound as a sealed plastic box. You can add more boxes (coefficients). You cannot open a box and change the atoms inside (subscripts).

Common mistake

Changing a subscript to balance an equation. H2O to H4O matches the hydrogens, but it names a substance that is not water.

Balance the beam. Conserve the atoms.

Pick a reaction. Move the coefficient sliders and watch the molecules fill the pans. When the atom counts match on both sides, the beam levels.

Interactive tool

Which coefficients make the atoms match on both sides?

Equation1 H₂ + 1 O₂ → 1 H₂O
Hydrogen atoms2 = 2
Oxygen atoms2 ≠ 1
Not balanced yet

Oxygen: 2 on the left and 1 on the right. Change a coefficient, never a subscript.

  • Hydrogen atom
  • Oxygen atom
  • Nitrogen atom
  • Carbon atom

Predict the coefficients.

Fill the blanks from memory.

Type each blank from memory, then press Check. Press Show answers after your first check if you are stuck.

A reaction where a fuel reacts with oxygen to make CO2 and H2O is . A reaction where one reactant breaks into several products is . Equations must be balanced because of the Law of . The numbers in front of formulas that balance an equation are . The subscripts inside a formula fix the substance's .

Why lock the subscripts?

Balance a thermal decomposition.

Give yourself 1 mark for each idea you wrote down.

Gen Chem · HS-PS1-7 · constructed response [3 marks]
Why This Matters

An airbag depends on a balanced equation. In a crash, a sensor triggers the decomposition of solid sodium azide (NaN₃). Balancing the equation shows how a small pellet makes a large volume of nitrogen gas (N₂) in milliseconds.

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